1,2-Hydroxylamino Oximes and Pyrazine N,N-Dioxides
Document Type
Article
Publication Date
8-1-1970
Description
1,2-Nitroximes obtained from the isomerization of olefin-dinitrogen trioxide adducts are selectively reduced with palladized carbon to afford 1,2-hydroxylamino oximes. The latter class of compounds can be reduced to vicinal diamines, oxidized to 1,2-dioximes, form stable chelates with mercuric salts, and undergo a novel acid-catalyzed autocondensation to pyrazine N,N-dioxides.
Citation Information
Scheinbaum, M. L.. 1970. 1,2-Hydroxylamino Oximes and Pyrazine N,N-Dioxides. Journal of Organic Chemistry. Vol.35(8). 2790-2792. https://doi.org/10.1021/jo00833a070 ISSN: 0022-3263