One-Dimensional Phase Transitions in the Spherical Lattice Gas From Inverse Power Law Potentials

Document Type

Article

Publication Date

1-1-1970

Description

The spherical model of the lattice gas of Gersch and Berlin is studied by making an integral approximation to the Fourier coefficients of the interaction potential. A phase transition is found in one dimension for potentials -gr -a with 1 < α < 2. A necessary condition which a potential must satisfy to allow a 1-dimensional phase transition is given. General expressions are derived for specific heat Cv and isothermal compressibility KT. Discontinuities are found in the thermodynamic properties at the transition for α less than 3/2 times the number of dimensions. Asymptotic expansions are given for Cv and KT near the critical point.

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