An Ab Initio Study of OCCN and OCCN+

Document Type

Article

Publication Date

9-8-1997

Description

The structure and vibrational frequencies are reported for the OCCN radical and its cation using quadratic configuration interaction and complete active space self-consistent field methods. The heat of formation for the OCCN radical is estimated as 50.2 kcal mol-1. The adiabatic ionization potential is estimated as 8.5 eV. Vertical excitation energies for low-lying excited states of OCCN are also reported.

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