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Degree Name
MS (Master of Science)
Program
Chemistry
Date of Award
12-2004
Committee Chair or Co-Chairs
Mian Jiang
Committee Members
Chu-Ngi Ho, Hamid S. Kasmai
Abstract
Recently there have been considerable interests in nanometerial study. In this work, we have used carbon nanotubes (CNTs) and polypyrrole (PPy) conducting polymers (CPs) as models to make a nanotube and conducting polymer composite material. Under electro-oxidation condition, the PPy/CNT films can be grown on conventional substrates such as a glassy carbon electrode in aqueous and non-aqueous media. These nano-conjugated materials are based on the doping of CNTs particles into conducting polymer network while oxidatively polymerizing. CNTs serve as dopants and solely supporting electrolytes in the preparation. The CP/CNT new composite materials have showed promise not only in a potential environmental remedy such as conversion of highly toxic Cr(VI) into less harmful Cr(III), but also in electrocatalysis of the quinone/hydroquinone redox reaction. Voltammetry, bulk electrolysis with coulometry, AC impedance, and EQCM techniques have been used to elucidate the preparation, ion transport, and intermolecular interaction processes within these composites.
Document Type
Thesis - restricted
Recommended Citation
Oh, Jungmin, "Preparation and Application of Conducting Polymer-Carbon Nanotube Composite." (2004). Electronic Theses and Dissertations. Paper 960. https://dc.etsu.edu/etd/960
Copyright
Copyright by the authors.