Degree Name
MS (Master of Science)
Program
Chemistry
Date of Award
5-2020
Committee Chair or Co-Chairs
Catherine E. McCusker
Committee Members
Dane W. Scott, Greg Bishop
Abstract
Much of the energy used in the United States and around the globe is obtained from petroleum, natural gas, and coal. Photocatalytic CO2 reduction can be used to transform CO2 to useful fuels and making fossil fuels more renewable. Input of energy is required, and the sun can provide the required energy for this transformation. Photosensitizer, catalyst, and electron donor are required for photocatalytic CO2 reduction.
Due to lack of earth-abundant sensitizers, zinc dipyrrin complexes were synthesized by previous group members and have been used as photosensitizers in this research. The ground and excited state electrochemical properties of two zinc dipyrrin complexes were determined in polar and nonpolar solvents and the measured potentials were used to match the zinc sensitizers with an energetically appropriate iron porphyrin catalyst and a benzylthiol sacrificial electron donor. Lastly, pure CO2 gas was used as the source of carbon for the reduction of CO2 by photocatalysis with the zinc photosensitizers, iron catalyst and sacrificial electron donor. The products formed in headspace were analyzed by GC
Document Type
Thesis - unrestricted
Recommended Citation
Rasheed, Senan, "Photocatalytic Carbon Dioxide Reduction with Zinc(II) Dipyrrin Photosensitizers and Iron Catalyst" (2020). Electronic Theses and Dissertations. Paper 3730. https://dc.etsu.edu/etd/3730
Copyright
Copyright by the authors.